Combustion

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		A	n	E
C₂H Reactions
6.1	CH₂ + C ⇄ C₂H + H	5.00 × 10¹³	0.00	0.00
6.2	C₂H + O ⇄ CH + CO	5.00 × 10¹³	0.00	0.00
6.3	C₂H + O₂ ⇄ HCO + CO	2.41 × 10¹²	0.00	0.00
HCCO Reactions
6.4	HCCO + H ⇄ ¹CH₂ + CO	1.00 × 10¹⁴	0.00	0.00
6.5	C₂H + OH ⇄ HCCO + H	2.00 × 10¹³	0.00	0.00
6.6	HCCO + O ⇄ H + CO + CO	1.00 × 10¹⁴	0.00	0.00
6.7	C₂H + O₂ ⇄ HCCO + O	6.02 × 10¹¹	0.00	0.00
6.8	HCCO + O₂ ⇄ CO + CO + OH	1.60 × 10¹²	0.00	3.58
C₂H₂ Reactions
6.9	C₂H₂ + M ⇄ C₂H + H + M	7.46 × 10³⁰	−3.70	531.78
6.10	CH₃ + C ⇄ C₂H₂ + H	5.00 × 10¹³	0.00	0.00
6.11	CH₂ + CH ⇄ C₂H₂ + H	4.00 × 10¹³	0.00	0.00
6.12	C₂H + H₂ ⇄ C₂H₂ + H	4.09 × 10₅	2.39	3.61
6.13	C₂H₂ + O ⇄ CH₂ + CO	1.02 × 10⁷	2.00	7.95
6.14	C₂H₂ + O ⇄ C₂H + OH	3.16 × 10¹⁵	−0.60	62.76
6.15	C₂H₂ + O ⇄ HCCO + H	1.02 × 10⁷	2.00	7.95
6.16	C₂H₂ + OH ⇄ CH₃ + CO	4.83 × 10⁻⁴	4.00	−8.37
6.17	C₂H₂ + OH ⇄ C₂H + H₂O	3.38 × 10⁷	2.00	58.58
6.18	CH₂ + CH₂ ⇄ C₂H₂ + H₂	4.00 × 10¹³	0.00	0.00
6.19	C₂H₂ + O₂ ⇄ C₂H + HO₂	1.20 × 10¹³	0.00	311.75
6.20	C₂H₂ + O₂ ⇄ HCCO + OH	2.00 × 10⁸	1.50	125.94
6.21	HCCO + CH ⇄ C₂H₂ + CO	5.00 × 10¹³	0.00	0.00
6.22	HCCO + HCCO ⇄ C₂H₂ + ₂CO	1.00 × 10¹³	0.00	0.00
C₂H₃ Reactions
6.23^b	C₂H₂ + H ⇄ C₂H₃, k_∞	5.54 × 10¹²	0.00	10.08
	C₂H₂ + H + M ⇄ C₂H₃ + M, k₀	2.67 × 10²⁷	−3.50	10.08
	$ε_{H_{2}}$ $ε_{H_{2}}$ = 2, ε_CO = 2, $ε_{H_{2} O}$ $ε_{H_{2} O}$ = 5, $ε_{{CO}_{2}}$ $ε_{{CO}_{2}}$ = 3
6.24	C₂H₃ + H ⇄ C₂H₂ + H₂	1.20 × 10¹³	0.00	0.00
6.25	CH₃ + CH ⇄ C₂H₃ + H	3.00 × 10¹³	0.00	0.00
6.26	C₂H₃ + OH ⇄ C₂H₂ + H₂O	3.00 × 10¹³	0.00	0.00
6.27	C₂H₃ + O₂ ⇄ HCO + HCO + H	3.27 × 10²³	−3.94	20.96
6.28^c	C₂H₃ + O₂ ⇄ CH₂O + HCO	4.48 × 10²⁶	−4.55	22.93
		1.05 × 10³⁸	−8.22	29.41
6.29	C₂H₃ + O₂ ⇄ C₂H₂ + HO₂	5.10 × 10²¹	−3.24	23.68
6.30	HCCO + CH₂ ⇄ C₂H₃ + CO	3.00 × 10¹³	0.00	0.00
Table Continued

		A	n	E
6.31	C₂H₃ + CH ⇄ C₂H₂ + CH₂	5.00 × 10¹³	0.00	0.00
6.32	C₂H₃ + CH₃ ⇄ C₂H₂ + CH₄	3.90 × 10¹¹	0.00	0.00
6.33	C₂H₃ + C₂H₃ ⇄ C₂H₄ + C₂H₂	9.60 × 10¹¹	0.00	0.00
HCCOH Reactions
6.34	C₂H₂ + OH ⇄ HCCOH + H	5.04 × 10⁵	2.30	56.49
CH₂CO Reactions
6.35	CH₂CO ⇄ CH₂ + CO, k_∞	3.00 × 10¹⁴	0.00	297.00
	CH₂CO + M ⇄ CH₂ + CO + M, k₀	3.60 × 10¹⁵	0.00	247.99
6.36	CH₂CO + H ⇄ CH₃ + CO	1.13 × 10¹³	0.00	14.34
6.37	CH₂CO + H ⇄ HCCO + H₂	5.00 × 10¹³	0.00	33.47
6.38	C₂H₂ + OH ⇄ CH₂CO + H	2.18 × 10⁻⁴	4.50	−4.18
6.39	C₂H₃ + O ⇄ CH₂CO + H	3.00 × 10¹³	0.00	0.00
6.40	CH + CH₂O ⇄ CH₂CO + H	9.46 × 10¹³	0.00	−2.15
6.41	HCCOH + H ⇄ CH₂CO + H	1.00 × 10¹³	0.00	0.00
6.42	CH₂CO + O ⇄ CH₂ + CO₂	1.75 × 10¹²	0.00	5.65
6.43	CH₂CO + O ⇄ HCCO + OH	1.00 × 10¹³	0.00	33.47
6.44	CH₂CO + OH ⇄ HCCO + H₂O	7.50 × 10¹²	0.00	8.37
6.45	C₂H₃ + HO₂ ⇄ CH₂CO + OH + H	3.00 × 10¹³	0.00	0.00
CH₃CO Reactions
6.46	CH₃CO ⇄ CH₃ + CO, k_∞	1.20 × 10²²	−3.04	78.66
	CH₃CO + M ⇄ CH₃ + CO + M, k₀	8.73 × 10⁴²	−8.62	93.72
6.47	CH₃CO + H ⇄ CH₃ + HCO	9.60 × 10¹³	0.00	0.00
6.48	CH₃CO + O ⇄ CH₃ + CO₂	9.60 × 10¹²	0.00	0.00
6.49	CH₃CO + OH ⇄ CH₃ + CO + OH	3.00 × 10¹³	0.00	0.00
6.50	CH₃CO + OH ⇄ CH₂CO + H₂O	1.20 × 10¹³	0.00	0.00
6.51	CH₃CO + HO₂ ⇄ CH₃ + CO₂ + OH	3.00 × 10¹³	0.00	0.00
C₂H₄ Reactions
6.52	C₂H₄ + M ⇄ C₂H₂ + H₂ + M	1.50 × 10¹⁵	0.44	233.48
6.53	C₂H₄ + M ⇄ C₂H₃ + H + M	1.40 × 10¹⁶	0.00	344.61
6.54	C₂H₄ + H ⇄ C₂H₃ + H₂	1.10 × 10¹⁴	0.00	35.57
6.55	CH₄ + CH ⇄ C₂H₄ + H	6.00 × 10¹³	0.00	0.00
6.56	CH₃ + CH₂ ⇄ C₂H₄ + H	3.00 × 10¹³	0.00	0.00
6.57	C₂H₄ + O ⇄ CH₃ + HCO	1.60 × 10⁹	1.20	3.12
6.58	C₂H₄ + OH ⇄ C₂H₃ + H₂O	2.02 × 10¹³	0.00	24.92
6.59	C₂H₄ + O₂ ⇄ C₂H₃ + HO₂	4.22 × 10¹³	0.00	241.00
6.60	C₂H₄ + CH₃ ⇄ C₂H₃ + CH₄	6.62	3.70	39.75
6.61	CH₃ + CH₃ ⇄ C₂H₄ + H₂	1.00 × 10¹⁶	0.00	139.91
Table Continued

		A	n	E
C₂H₄O Reactions
6.62	C₂H₄O ⇄ CH₄ + CO	3.16 × 10¹⁴	0.00	238.49
6.63	C₂H₄ + HO₂ ⇄ C₂H₄O + OH	6.00 × 10⁹	0.00	33.26
CH₃CHO Reactions
6.64	CH₃CHO ⇄ CH₃ + HCO	7.08 × 10¹⁵	0.00	342.10
6.65	C₂H₃ + OH ⇄ CH₃CHO	3.00 × 10¹³	0.00	0.00
6.66	CH₃CHO + H ⇄ CH₃CO + H₂	4.00 × 10¹³	0.00	17.60
6.67	CH₃CHO + O ⇄ CH₃CO + OH	5.00 × 10¹²	0.00	7.50
6.68	CH₃CHO + OH ⇄ CH₃CO + H₂O	1.00 × 10¹³	0.00	0.00
6.69	CH₃CHO + O₂ ⇄ CH₃CO + HO₂	2.00 × 10¹³	0.50	176.56
6.70	CH₃CHO + HO₂ ⇄ CH₃CO + H₂O₂	1.70 × 10¹²	0.00	44.77
6.71	CH₃CHO + CH₃ ⇄ CH₃CO + CH₄	1.74 × 10¹²	0.00	35.31
C₂H₅ Reactions
6.72	C₂H₅ ⇄ C₂H₄ + H, k_∞	4.90 × 10⁹	1.19	155.64
	C₂H₅ + M ⇄ C₂H₄ + H + M, k₀	5.10 × 10⁶⁴	−14.00	251.46
6.73	CH₃ + CH₃ ⇄ C₂H₅ + H	8.00 × 10¹⁵	0.00	110.93
6.74	C₂H₅ + H ⇄ C₂H₄ + H₂	1.81 × 10¹²	0.00	0.00
6.75	C₂H₅ + O ⇄ CH₂O + CH₃	1.60 × 10¹³	0.00	0.00
6.76	C₂H₅ + O ⇄ CH₃HCO + H	9.60 × 10¹⁴	0.00	0.00
6.77	C₂H₅ + OH ⇄ CH₃ + CH₂O + H	2.40 × 10¹³	0.00	0.00
6.78	C₂H₅ + OH ⇄ C₂H₄ + H₂O	2.40 × 10¹³	0.00	0.00
6.79	C₂H₅ + O₂ ⇄ C₂H₄ + HO₂	2.56 × 10¹⁹	−2.77	8.27
6.80	C₂H₅ + HO₂ ⇄ CH₃ + CH₂O + OH	2.40 × 10¹³	0.00	0.00
6.81	C₂H₅ + HO₂ ⇄ C₂H₄ + H₂O₂	3.00 × 10¹¹	0.00	0.00
C₂H₆ Reactions
6.82^b^,^d	CH₃ + CH₃ ⇄ C₂H₆, k_∞	9.21 × 10¹⁶	−1.17	2.67
	CH₃ + CH₃ + M ⇄ C₂H₆ + M, k₀	1.14 × 10³⁶	−5.25	7.13
	F_c = (−0.64)exp(−T/6927) + 0.64exp(−132/T)
	$ε_{H_{2}}$ $ε_{H_{2}}$ = 2, $ε_{H_{2} O}$ $ε_{H_{2} O}$ = 5, ε_CO = 2, $ε_{{CO}_{2}}$ $ε_{{CO}_{2}}$ = 3
6.83	C₂H₆ ⇄ C₂H₅ + H	2.08 × 10³⁸	−7.08	445.60
6.84	C₂H₆ + H ⇄ C₂H₅ + H₂	5.42 × 10²	3.50	21.80
6.85	C₂H₆ + O ⇄ C₂H₅ + OH	3.00 × 10⁷	2.00	21.40
6.86	C₂H₆ + OH ⇄ C₂H₅ + H₂O	5.13 × 10⁶	2.06	3.57
6.87	C₂H₆ + O₂ ⇄ C₂H₅ + HO₂	4.00 × 10¹³	0.00	213.00
6.88	C₂H₆ + HO₂ ⇄ C₂H₅ + H₂O₂	2.94 × 10¹¹	0.00	62.51
6.89	C₂H₆ + ¹CH₂ ⇄ C₂H₅ + CH₃	1.20 × 10¹⁴	0.00	0.00
6.90	C₂H₆ + CH₃ ⇄ C₂H₅ + CH₄	5.50 × 10⁻¹	4.00	34.73
Table Continued

		A	n	E
6.91	C₂H₆ + C₂H₃ ⇄ C₂H₅ + C₂H₄	6.00 × 10²	3.30	43.93
6.92	C₂H₅ + C₂H₅ ⇄ C₂H6 + C₂H4	1.40 × 10¹²	0.00	0.00

Miller JA, Bowman CT. Mechanism and modeling of nitrogen chemistry in combustion. Prog Energy Combust Sci 1989;15:287–338. Li J, Zhao Z, Kazakov A, Chaos M, Dryer FL, Scire Jr JJ. A comprehensive kinetic mechanism for CO, CH₂O, and CH₃OH combustion. Int J Chem Kinet 2007;39:109–36. Held T. The oxidation of methanol, isobutene, and methyl tertiary-butyl ether, No. 1978-T, PhD dissertation, Princeton University, Princeton, NJ 08544, 1993. Burgess Jr DRF, Zachariah MR, Tsang W, Westmoreland PR. Thermochemical and chemical kinetic data for fluorinated hydrocarbons, NIST technical note 1412, NIST, Gaithersburg, MD, 1995.

Table C7

Selected Reactions of a C₃H₈ Oxidation Mechanism^a

		A	n	E
C₃H₈ Reactions
7.1	C₃H₈ ⇄ C₂H₅ + CH₃	7.90 × 10²²	−1.80	371.10
7.2	C₃H₈ + H ⇄ n-C₃H₇ + H₂	1.33 × 10⁶	2.54	28.27
7.3	C₃H₈ + H ⇄ i-C₃H₇ + H₂	1.30 × 10⁶	2.40	18.71
7.4	C₃H₈ + O ⇄ n-C₃H₇ + OH	1.93 × 10⁵	2.68	15.55
7.5	C₃H₈ + O ⇄ i-C₃H₇ + OH	4.76 × 10⁴	2.71	8.81
7.6	C₃H₈ + OH ⇄ n-C₃H₇ + H₂O	1.05 × 10¹⁰	0.97	13.19
7.7	C₃H₈ + OH ⇄ i-C₃H₇ + H₂O	4.67 × 10⁷	1.61	−0.29
7.8	C₃H₈ + O₂ ⇄ n-C₃H₇ + HO₂	3.98 × 10¹³	0.00	213.10
7.9	C₃H₈ + O₂ ⇄ i-C₃H₇ + HO₂	3.98 × 10¹³	0.00	199.10
7.10	C₃H₈ + HO₂ ⇄ n-C₃H₇ + H₂O₂	4.75 × 10⁴	2.55	69.00
7.11	C₃H₈ + HO₂ ⇄ i-C₃H₇ + H₂O₂	9.64 × 10³	2.60	58.20
7.12	C₃H₈ + CH₃ ⇄ n-C₃H₇ + CH₄	9.03 × 10⁻¹	3.65	59.47
7.13	C₃H₈ + CH₃ ⇄ i-C₃H₇ + CH₄	1.51	3.46	45.56
n-C₃H₇ Reactions
7.14	n-C₃H₇ ⇄ C₂H₄ + CH₃	1.26 × 10¹³	0.00	252.75
7.15	n-C₃H₇ ⇄ C₃H₆ + H	1.12 × 10¹³	0.00	293.23
7.16	n-C₃H₇ + O₂ ⇄ C₃H₆ + HO₂	1.17 × 10¹⁹	−1.59	112.16
7.17	n-C₃H₇ + O₂ ⇄ C₂H₄ + CH₂O + OH	2.44 × 10¹⁶	−0.95	178.58
Table Continued

		A	n	E
i-C₃H₇ Reactions
7.18	i-C₃H₇ ⇄ C₂H₄ + CH₃	2.00 × 10¹⁰	0.00	245.26
7.19	i-C₃H₇ ⇄ C₃H₆ + H	4.00 × 10¹³	0.00	317.59
7.20	i-C₃H₇ + O₂ ⇄ C₃H₆ + HO₂	2.69 × 10²⁷	−4.60	117.56
C₃H₆ Reactions
7.21	C₃H₆ ⇄ C₃H₅ + H	2.50 × 10¹⁵	0.00	362.68
7.22	C₃H₆ ⇄ C₂H₃ + CH₃	1.10 × 10²¹	−1.20	408.80
7.23	C₃H₆ + H ⇄ C₃H₅ + H₂	1.73 × 10⁵	2.50	20.70
7.24	C₃H₆ + H ⇄ CHCHCH₃ + H₂	8.07 × 10⁵	2.50	102.10
7.25	C₃H₆ + H ⇄ CH₃CCH₂ + H₂	4.10 × 10⁵	2.50	81.43
7.26	C₃H₆ + O ⇄ C₃H₅ + OH	1.75 × 10¹¹	0.70	48.91
7.27	C₃H₆ + O ⇄ CHCHCH₃ + OH	1.20 × 10¹¹	0.70	74.49
7.28	C₃H₆ + O ⇄ CH₃CCH₂ + OH	6.02 × 10¹⁰	0.70	63.45
7.29	C₃H₆ + O ⇄ CH₂CO + CH₃ + H	7.80 × 10⁷	1.83	3.12
7.30	C₃H₆ + O ⇄ CH₃CHCO + ₂H	3.90 × 10⁷	1.83	3.12
7.31^b	C₃H₆ + O ⇄ C₂H₅ + HCO	3.49 × 10⁷	1.83	−2.29
		−1.17 × 10⁷	1.83	3.12
7.32	C₃H₆ + OH ⇄ C₃H₅ + H₂O	3.12 × 10⁶	2.00	−2.47
7.33	C₃H₆ + OH ⇄ CHCHCH₃ + H₂O	2.14 × 10⁶	2.00	11.62
7.34	C₃H₆ + OH ⇄ CH₃CCH₂ + H₂O	1.11 × 10⁶	2.00	6.07
7.35	C₃H₆ + O₂ ⇄ C₃H₅ + HO₂	6.02 × 10¹³	0.00	199.10
7.36	C₃H₆ + HO₂ ⇄ C₃H₅ + H₂O₂	9.64 × 10³	2.60	58.20
7.37	C₃H₆ + CH₃ ⇄ C₃H₅ + CH₄	2.22	3.50	23.74
7.38	C₃H₆ + CH₃ ⇄ CHCHCH₃ + CH₄	1.35	3.50	53.76
7.39	C₃H₆ + CH₃ ⇄ CH₃CCH₂ + CH₄	8.42 × 10⁻¹	3.50	4.88
CHCHCH₃ Reactions
7.40	CHCHCH₃ ⇄ C₂H₂ + CH₃	1.59 × 10¹²	0.00	156.90
7.41	CHCHCH₃ + H ⇄ C₃H₄ + H₂	3.33 × 10¹²	0.00	0.00
7.42	CHCHCH₃ + O₂ ⇄ CH₃HCO + HCO	4.34 × 10¹²	0.00	0.00
7.43	CHCHCH₃ + CH₃ ⇄ C₃H₄ + CH₄	1.00 × 10¹¹	0.00	0.00
CH₂CCH₃ Reactions
7.44	CH₂CCH₃ + H ⇄ pC₃H₄ + H₂	3.33 × 10¹²	0.00	0.00
7.45	CH₂CCH₃ + O₂ ⇄ CH₂O + CH₃CO	4.34 × 10¹²	0.00	0.00
7.46	CH₂CCH₃ + CH₃ ⇄ pC₃H₄ + CH₄	1.00 × 10¹¹	0.00	0.00
C₃H₅ Reactions
7.47	C₃H₅ ⇄ C₃H₄ + H	1.40 × 10¹³	0.00	251.00
7.48	C₃H₅ + H ⇄ C₃H₄ + H₂	1.80 × 10¹³	0.00	0.00
Table Continued

		A	n	E
7.49	C₃H₅ + O ⇄ C₂H₃HCO + H	6.02 × 10¹³	0.00	0.00
7.50	C₃H₅ + OH ⇄ C₃H₄ + H₂O	6.02 × 10¹²	0.00	0.00
7.51	C₃H₅ + O₂ ⇄ C₃H₄ + HO₂	1.33 × 10⁷	0.00	0.00
7.52	C₃H₅ + HO₂ ⇄ C₂H₃HCO + OH + H	1.92 × 10¹¹	0.00	0.00
7.53	C₃H₅ + CH₃ ⇄ C₃H₄ + CH₄	3.00 × 10¹²	−0.32	−1.10
C₃H₄ Reactions
7.54	C₃H₄ ⇄ pC₃H₄	1.20 × 10¹⁵	0.00	386.60
7.55	C₃H₄ + M ⇄ C₃H₃ + H + M	1.14 × 10¹⁷	0.00	292.90
7.56	C₃H₄ + H ⇄ C₃H₃ + H₂	3.36 × 10⁻⁷	6.00	7.08
7.57	C₃H₄ + H ⇄ CH₂CCH₃	8.50 × 10¹²	0.00	8.37
7.58	C₃H₄ + O ⇄ CH₂O + C₂H₂	3.00 × 10⁻³	4.61	−17.75
7.59	C₃H₄ + O ⇄ CO + C₂H₄	9.00 × 10⁻³	4.61	−17.75
7.60	C₃H₄ + OH ⇄ C₃H₃ + H₂O	1.45 × 10¹³	0.00	17.45
7.61	C₃H₄ + OH ⇄ CH₂CO + CH₃	3.12 × 10¹²	0.00	−1.66
7.62	C₃H₄ + O₂ ⇄ C₃H₃ + HO₂	4.00 × 10¹³	0.00	257.32
7.63	C₃H₄ + HO₂ ⇄ CH₂CO + CH₂ + OH	4.00 × 10¹²	0.00	79.50
7.64	C₃H₄ + CH₃ ⇄ C₃H₃ + CH₄	2.00 × 10¹²	0.00	32.22
p-C₃H₄ Reactions
7.65	pC₃H₄ + M ⇄ C₃H₃ + H + M	1.00 × 10¹⁷	0.00	292.88
7.66	pC₃H₄ ⇄ C₂H + CH₃	4.20 × 10¹⁶	0.00	418.40
7.67	pC₃H₄ + H ⇄ C₃H₃ + H₂	1.00 × 10¹²	0.00	6.28
7.68	pC₃H₄ + H ⇄ CH₂CCH₃	6.50 × 10¹²	0.00	8.37
7.69	pC₃H₄ + H ⇄ CHCHCH₃	5.80 × 10¹²	0.00	12.97
7.70	pC₃H₄ + O ⇄ C₂H₂ + CO + H₂	1.50 × 10¹³	0.00	8.83
7.71	pC₃H₄ + O ⇄ CH₂CO + CH₂	3.20 × 10¹²	0.00	8.41
7.72	pC₃H₄ + O ⇄C₂H₃ + HCO	3.20 × 10¹²	0.00	8.41
7.73	pC₃H₄ + O ⇄ C₂H₄ + CO	3.20 × 10¹²	0.00	8.41
7.74	pC₃H₄ + O ⇄ HCCO + CH₃	6.30 × 10¹²	0.00	8.41
7.75	pC₃H₄ + O ⇄ HCCO + CH₂ + H	3.20 × 10¹¹	0.00	8.41
7.76	pC₃H₄ + OH ⇄ C₃H₃ + H₂O	1.50 × 10³	3.00	0.84
7.77	pC₃H₄ + OH ⇄ CH₂CO + CH₃	5.00 × 10⁻⁴	4.50	−4.18
7.78	pC₃H₄ + O₂ ⇄ C₃H₃ + HO₂	2.50 × 10¹²	0.00	213.38
7.79	pC₃H₄ + O₂ ⇄ HCCO + OH + CH₂	1.00 × 10⁷	1.50	125.94
7.80	pC₃H₄ + HO₂ ⇄ C₂H₄ + CO + OH	3.00 × 10¹²	0.00	79.50
7.81	pC₃H₄ + CH₃ ⇄ C₃H₃ + CH₄	2.00 × 10¹²	0.00	32.22
c-C₃H₄ Reactions
7.82	cC₃H₄ ⇄ C₃H₄	1.51 × 10¹⁴	0.00	210.90
7.83	cC₃H₄ ⇄ pC₃H₄	1.20 × 10¹⁵	0.00	182.80
Table Continued

		A	n	E
C₃H₃ Reactions
7.84	CH₂ + C₂H₂ ⇄ C₃H₃ + H	1.20 × 10¹³	0.00	27.61
7.85	¹CH₂ + C₂H₂ ⇄ C₃H₃ + H	3.00 × 10¹³	0.00	0.00
7.86	C₃H₃ + O ⇄ CH₂O + C₂H	2.00 × 10¹³	0.00	0.00
7.87	C₃H₃ + OH ⇄ C₃H₂ + H₂O	2.00 × 10¹³	0.00	0.00
7.88	C₃H₃ + O₂ ⇄ CH₂CO + HCO	3.00 × 10¹⁰	0.00	12.00
7.89	C₃H₃ + CH₃ ⇄ C₂H₅ + C₂H	1.00 × 10¹³	0.00	156.90
7.90	C₃H₃ + C₃H₃ C₂H₂ + C₂H₂ + C₂H₂	5.00 × 10¹¹	0.00	0.00
C₃H₂ Reactions
7.91	CH + C₂H₂ ⇄ C₃H₂ + H	1.00 × 10¹⁴	0.00	0.00
7.92	C₃H₂ + O₂ ⇄ HCCO + HCO	1.00 × 10¹³	0.00	0.00

Table C8

N_xO_y/CO/H₂/O₂ Mechanism^a

		A	n	E
N and NO Reactions
8.1	NO + M ⇄ N + O + M	9.64 × 10¹⁴	0.00	620.91
8.2	NO + H ⇄ N + OH	1.69 × 10¹⁴	0.00	204.18
8.3	NO + O ⇄ N + O₂	1.81 × 10⁹	1.00	162.13
8.4	N + HO₂ ⇄ NO + OH	1.00 × 10¹³	0.00	8.39
8.5	NO + N ⇄ N₂ + O	3.27 × 10¹²	0.30	0.00
NO₂ Reactions
8.6^b^,^d	NO + O ⇄ NO₂, k_∞	1.30 × 10¹⁵	−0.75	0.00
	NO + O + M ⇄ NO₂ + M, k₀	4.72 × 10²⁴	−2.87	6.49
	NO + O + Ar ⇄ NO₂ + Ar, k₀	7.56 × 10¹⁹	−1.41	0.00
	F_c = 0.95–1.0 × 10⁻⁴T
8.7	NO₂ + H ⇄ NO + OH	1.32 × 10¹⁴	0.00	1.51
8.8	NO₂ + O ⇄ NO + O₂	3.91 × 10¹²	0.00	−1.00
8.9	NO₂ + OH ⇄ NO + HO₂	1.81 × 10¹³	0.00	27.93
8.10	NO₂ + CO ⇄ NO + CO₂	9.03 × 10¹³	0.00	141.34
8.11	NO₂ + HCO ⇄ NO + H + CO₂	8.39 × 10¹⁵	−0.75	8.06
Table Continued

		A	n	E
8.12	NO₂ + N ⇄ N₂ + O₂	1.00 × 10¹²	0.00	0.00
8.13	NO₂ + N ⇄ NO + NO	4.00 × 10¹²	0.00	0.00
8.14	NO₂ + NO₂ ⇄ 2NO + O₂	1.63 × 10¹²	0.00	109.29
N₂O Reactions
8.15^b	N₂O ⇄ N₂ + O, k_∞	7.91 × 10¹⁰	0.00	234.39
	N₂O + M ⇄ N₂ + O + M, k₀	9.13 × 10¹⁴	0.00	241.42
	ε_Ar = 0.63, $ε_{H_{2} O}$ $ε_{H_{2} O}$ = 7.5
8.16^c	N₂O + H ⇄ N₂ + OH	2.53 × 10¹⁰	0.00	19.04
		2.23 × 10¹⁴	0.00	70.08
8.17	N₂O + O ⇄ N₂ + O₂	1.00 × 10¹⁴	0.00	117.15
8.18	N₂O + O ⇄ NO + NO	1.00 × 10¹⁴	0.00	117.15
8.19	NO₂ + N ⇄ N₂O + O	5.00 × 10¹²	0.00	0.00
8.20	N₂O + OH ⇄ N₂ + HO₂	2.00 × 10¹²	0.00	167.36
8.21	N₂O + CO ⇄ N₂ + CO₂	5.01 × 10¹³	0.00	184.10
8.22	N₂O + N ⇄ N₂ + NO	1.00 × 10¹³	0.00	83.14
8.23	N₂O + NO ⇄ N₂ + NO₂	1.00 × 10¹⁴	0.00	209.20
HNO Reactions
8.24^b^,^d	NO + H ⇄ HNO, k_∞	1.52 × 10¹⁵	−0.41	0.00
	NO + H + M ⇄ HNO + M, k₀	8.96 × 10¹⁹	−1.32	3.08
	F_c = 0.82
	ε_Ar = 0.63
8.25	HNO + H ⇄ NO + H₂	4.46 × 10¹¹	0.72	2.74
8.26	HNO + O ⇄ NO + OH	1.81 × 10¹³	0.00	0.00
8.27	HNO + OH ⇄ NO + H₂O	1.30 × 10⁷	1.88	−4.00
8.28	NO + HCO ⇄ HNO + CO	7.23 × 10¹²	0.00	0.00
8.29	HNO + HCO ⇄ NO + CH₂O	6.02 × 10¹¹	0.00	8.31
8.30	HNO + N ⇄ N₂O + H	5.00 × 10¹⁰	0.50	12.55
8.31	HNO + NO ⇄ N₂O + OH	2.00 × 10¹²	0.00	08.78
8.32	HNO + HNO ⇄ N₂O + H₂O	8.51 × 10⁸	0.00	12.89
HONO Reactions
8.33^b^,^c^,^d	NO + OH ⇄ HONO, k_∞	1.99 × 10¹²	−0.05	−3.02
	NO + OH + M ⇄ HONO + M, k₀	5.08 × 10²³	−2.51	−0.28
	F_c = 0.62
	ε_Ar = 0.63
8.34	NO₂ + H₂ ⇄ HONO + H	3.21 × 10¹²	0.00	120.54
8.35	HONO + O ⇄ OH + NO₂	1.20 × 10¹³	0.00	24.94
8.36	HONO + OH ⇄ H₂O + NO₂	1.26 × 10¹⁰	1.00	0.57
8.37	NO₂ + HCO ⇄ HONO + CO	1.24 × 10²³	−7.29	9.85
8.38	NO₂ + CH₂O ⇄ HONO + HCO	7.83 × 10²	2.77	57.45
8.39	HNO + NO₂ ⇄ HONO + NO	6.02 × 10¹¹	0.00	8.31
Table Continued

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Table of Contents for
Combustion