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Woodhead Publishing Series in Energy

Part One. Key issues and assessment of biofuels production

1. Introduction: An overview of biofuels and production technologies

1.1. Introduction

1.2. Development of (bio)chemical conversion technologies

1.3. Development of biological conversion technologies

1.4. Thermochemical conversion technologies

1.5. Process integration and biorefinery

1.6. Future trends

2. Multiple objectives policies for biofuels production: Environmental, socio-economic, and regulatory issues

2.1. Introduction

2.2. Energy security and supply

2.3. Emission reductions, land use, and other environmental impacts

2.4. Food safety and development of rural areas

2.5. Biofuels support policies

2.6. Conclusions

3. Life cycle sustainability assessment of biofuels

3.1. Introduction

3.2. Main challenges for biofuel sustainability

3.3. Life cycle sustainability assessment methodology

3.4. LCA considerations of biomass to biofuel conversion routes

3.5. Overview of major findings of selected LCA studies in biofuel production

3.6. Conclusions

4. Biofuels: Technology, economics, and policy issues

4.1. Introduction

4.2. Moving from fossil fuel to biofuels: insights from socio-technical transition theory

4.3. Assessing first- and next-generation biofuels

4.4. Economic, environmental, and social issues

4.5. Policy actions and the regulatory framework

4.6. Conclusions

5. Feedstocks and challenges to biofuel development

5.1. Introduction

5.2. Edible vegetable raw materials for biodiesel production

5.3. Nonedible/low-cost raw materials for diesel engine biofuel production

5.4. Raw materials for bioethanol production

Part Two. Biofuels from chemical and biochemical conversion processes and technologies

6. Production of biodiesel via catalytic upgrading and refining of sustainable oleagineous feedstocks

6.1. Introduction

6.2. General background to biodiesel

6.3. Recent robust technology in biodiesel catalysis

6.4. Concluding remarks

7. Biochemical catalytic production of biodiesel

7.1. Introduction

7.2. Lipases

7.3. Enzymatic production of biodiesel

7.4. New tendencies in enzymatic production of biodiesel

7.5. Biofuels similar to biodiesel produced using several acyl acceptors, different to methanol

7.6. Industrial biodiesel production using enzymes

7.7. Conclusions

8. Production of fuels from microbial oil using oleaginous microorganisms

8.1. Introduction

8.2. Oleaginous yeasts and raw materials used for microbial oil production

8.3. The biochemistry of lipid accumulation in the oleaginous microorganisms

8.4. Microbial oil production in fed-batch cultures

8.5. Biodiesel production from microbial oil

8.6. Techno-economic evaluation of biodiesel production from microbial oil

8.7. Perspective of biofuel production from microbial oil

9. Biochemical production of bioalcohols

9.1. Introduction

9.2. Types of biomass for bioalcohol production

9.3. Bioalcohols

9.4. New technologies for bioethanol production

10. Production of biogas via anaerobic digestion

10.1. Introduction

10.2. Factors affecting the anaerobic digestion process

10.3. Advantages and limitations

10.4. Reactor configurations

10.5. Methods for enhancing the efficiency of anaerobic digestion

10.6. Process modeling

10.7. Process monitoring and control

10.8. Biogas utilization

10.9. Existing biogas installations

10.10. Conclusions and future trends

11. Biological and fermentative production of hydrogen

11.1. Introduction

11.2. Fundamentals of biohydrogen production

11.3. Biological hydrogen production strategies

11.4. Enhancing hydrogen production through metabolic engineering

11.5. Hydrogen production by cell-free enzymatic systems

11.6. Comparison of biohydrogen production techniques

11.7. Conclusions and outlook

12. Biological and fermentative conversion of syngas

12.1. Introduction

12.2. Fundamentals of syngas fermentation

12.3. Bacteria for syngas conversion

12.4. Effects of process parameters

12.5. Reactors for fermentative conversion of syngas

12.6. Product recovery

12.7. Examples of commercial and semicommercial processes

12.8. Conclusions for biological fermentation of syngas

13. Chemical routes for the conversion of cellulosic platform molecules into high-energy-density biofuels

13.1. Introduction

13.2. Oxygenated fuels via 5-HMF: furanic compounds

13.3. Levulinic acid as platform molecule to oxygenated fuels: alkyl levulinates and valeric biofuels

13.4. Oxygenated fuels via furfural: furan derivatives

13.5. Blending effect of oxygenated biofuels with conventional fuels

13.6. Catalytic conversion of γ-valerolactone to liquid hydrocarbon fuels

13.7. Furan derivatives as platform molecules for liquid hydrocarbon fuels

13.8. Sugars to hydrocarbon fuels: aqueous phase reforming process

13.9. Final remarks and future outlook

Part Three. Biofuels from thermal and thermo-chemical conversion processes and technologies

14. Catalytic fast pyrolysis for improved liquid quality

14.1. Introduction

14.2. Pyrolysis background

14.3. Catalytic pyrolysis

14.4. Catalytic pyrolysis: catalysts used

14.5. Catalytic pyrolysis: reactor setup

14.6. Conclusion and future opportunities

15. Production of bio-syngas and bio-hydrogen via gasification

15.1. Introduction

15.2. Biomass feedstock for gasification

15.3. Biomass gasification process

15.4. Gasification technology

15.5. Syngas technology: composition, conditioning and upgrading to valuable products

15.6. Current status in commercial gasification of biomass

15.7. Challenges and opportunities

16. Production of bioalcohols via gasification

16.1. Introduction

16.2. Gasification routes for alcohol production

16.3. Technical and economical analysis of the oxidative coupling of methane process

16.4. Conclusions and future perspectives

17. Production of biofuels via hydrothermal conversion

17.1. Introduction

17.2. Process chemistry

17.3. Process layout

17.4. Feedstock considerations

17.5. Product distribution and properties

17.6. Development of technology and current research

17.7. Lifecycle and techno-economic assessment

17.8. Conclusions

18. Production of biofuels via Fischer–Tropsch synthesis: Biomass-to-liquids

18.1. Introduction

18.2. Biomass-to-liquids process steps and technologies

18.3. Biomass-to-liquids final fuel products

18.4. Environmental and economic considerations of the BTL process

18.5. Commercial status of the biomass-to-liquids processes

18.6. Future prospects and challenges

19. Production of biofuels via bio-oil upgrading and refining

19.1. Introduction

19.2. Upgrading of biomass liquefaction products

19.3. Liquid fuel products from biomass through direct liquefaction and hydroprocessing

19.4. Conclusions

Part Four. Integrated production and application of biofuels

20. Biofuel production from food wastes

20.1. Introduction

20.2. Characteristics of food waste

20.3. Common food waste managements

20.4. Biofuels production

20.5. Conclusions and future trends

List of abbreviations

21. Biochar in thermal and thermochemical biorefineries—production of biochar as a coproduct

21.1. Introduction

21.2. Biochar as a coproduct in biofuels and bioenergy production

21.3. Biochar from biorefinery residues

22. Algae for biofuels: An emerging feedstock

22.1. Introduction

22.2. Microalgal biomass and oil

22.3. Oil biosynthesis in microalgae

22.4. Mass cultivation

22.5. Biomass harvesting and dewatering

22.6. Oil extraction and transesterification

22.7. Conclusions and future directions

23. Utilization of biofuels in diesel engines

23.1. Introduction

23.2. Utilization of vegetable pure plant oil and crude oil in diesel engines

23.3. Utilization of biodiesel-based palm oil, jatropha oil, coconut oil, and kapok nut oil in diesel engines

23.4. Utilization of biodiesel B5-based cat-fish fat in diesel engines

23.5. The concept of using biofuel on engines (prime mover)

23.6. Conclusion and remarks

Index

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